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rate at which it can escape through the core prints and

moulding walls, pressure "builds up until gas bubbles tin

ough the

metal

and may be trapped

beneath the skin of so

lid mo.tal,

if

solidification has

commenced,

or beneath a

core •

 

 

 

 

 

 

Gas holes

from these reasons are, as a rule,

readily dls

tinguished

from other

holes such as those duo to high ga

content

of

the

metal,

or £o metal-mould reactions.

They are

usually large

and well-rounded but

sometimes th

defect may

appear in a completely different form, for ea

ample,

like

misruns.

However

it

is mainly inherent in thin walls castings.

5- due to incomplete drying moulds and cores (at pouring the metal in dry sand moulds) or due to the higher moisture content (at pouring the metal in green sand moulds). Blow holes as the result of the high moist-» ure content usually occur when green sand moulds are used. In this case the main source of gas is the fre water, which, evaporates rapidly as soon as the tempei ature reaches 100°C. Gas is also given off by coaid and by the clay (combined water) but it takes place a temperatures higher than 400°C. Nevertheless it has determined in practice that the major constituent of gas is steam and its amount is great enough. That i

why, when the

permeability of cores

and green sand moulds

is IOVJ, blows

due to high moisture

content are inavitable .

They are also usually found underneath the top surface of the casting or beneath a core, and are frequently comple­ tely covered by a thin shell of metal, although they some­ times reach the surface. Their dimensions may be different depending on amount of gases, on the pouring temperature , and on the rate of their evolution,

6- as the result of the incorrect design of a gating sys­

tem leading to intensive stirring the metal at the process

of pouring and to entrapping of air with the molten metal

into the mould. Entrapped air is recognized as small, in­

ternally oxidized holes just beneath the cope surfacej it

.is found in aluminium and magnesium castings more freque­ ntly than in other cast metals,

7- by other sources of a gas evolution (soiled and rusty chills or chaplets due to their poor fusion with the basic metalj lumps of pitch or binders, when shell moulds and cores are used, as a result of nonuniform distribution-of binders in mixtures, and so on).

The reason of such defects can be

easily found

in

accord­

ance with the location of their ingate

holes*

the

ingate

holes of these

defects,

as a rule,

are

directed to

the side

of a source

the gas

evolution (

ch ill, chaplet,e^c).

Gas holes and porosity in castings can-be eli only at the severe observance of a technological 6i

at a ll stages of the casting production: from, makingn

and preparation

of an alloy upto cooling a casting.

Measures

of prevention of gas holes

and porosity in сг

ngs are

usually

divided into three

groups :

1- measures, preventing a saturation of a metal withg| during the process of melting.

In this case a preparation of qualitative ohargii materials is of a great umportance, For example, 1%oi rust in a steel charge brings about 2.5m? of gases per] 1 ton of liquid metal into a melting furnace. Thercfoi charge materials are to be carefully cleaned from rust moisture, and o il before melting.

 

In order to prevent gas absorption by alloys nit

furnace,

the melting

in

medium of

a protective gas is a

plied.

 

When alloys

are

used for

the

manufacture

of sji®

ia lly

responsible castings the charge

materials

are subj

ected

to

drying or tempering, but sometimes to vaouuatol

-before

melting.

 

 

 

 

 

 

 

The melting and pouring of

metals and alley-

for castings, in

v.’hich

a gas content must be minima-, a

usually

carried

out

in

vacuum melting-pouring asseibli'3

Titanium and its alloys, molybdenum, and special high-st­ rength alloys are melted and poured namely in that way.

The reducing of chances for absorptionoDf gas is

possible

by keeping

a ll items, that

must come into

cont­

act with

metal, dry,

and by melting

and ponring the

metal

at temperatures as low as possible to minimize gas solub­ ility .

2- It is usually impractical to prevent gas absorption en­

tirely . When it is impossible, the hazards

of dissolved

gases may be reduced by measures providing

a gas removal

or degassing of the molten metal before

its

pouring into

a mould or during the pouring process outside a melting

unit'^

They may be s remelting

a metal,

vacuuming

in

a la -

v*-*

 

 

 

 

 

 

 

die,

pouring in vacuum plants,

a treatment

of the

alloy by

supersound, flushing with

inert gases ( Fig.2.20).

 

 

 

The fir s t method of

gas

removal is

used at

the

alu­

minium alloy production.

Ip. this case,

the

fact

that

gases

are least soluble in cold, solid metal is applied, i.g .

gases

may be removal by a sequence of melting, slow cool­

ing, freezing, remelting and heating upto the needed tem­ perature of pouring. During the cooling and, especially, freezing dissolved gases are removed from the molten metal.

However', except in special cases, this method is too exp­

ensive

and time-consuming to bo used

in practice •

At tie

same time,

if

Sic-verts*law, according to which the

amount

of

gas

dissolved

in a molten metal depends on the press­

ure

of

this gas

above

and around the

metal,

is used in pri

ctice,

it

is

possible

to accelerate

the gas

removal from

the

metal by creating

a rarefied atmosphere

above

its sun

face in a ladle. Vacuum degassing the metal in a ladle

is an attempt to combine the advantages of melting in va­ cuum with the economy of air melting. Hare the metal is melted in air and then placed in an evacuated chamber(for degassing) before pouring. Pouring takes place in the op atmosphere.

Degassing alloys with the help of supersound emploies the seme principle of vacuum creating. Supersound waves of a high frequency impart to particles of a liquid metal elastic oscillations of a different value. As a result of the difference in rates ci moving particles a provisional rupture of solidity and formation of microvoides can be obtained. Dissolved gases rush to these ca­ vities to form bubbles. At the seад,once ruptures of the alloy* solidity bubbles increase upto critica l siaes.f loat out and are removed to the atmosphere.

Vacuum degassing

Fig. 2.20, Боте methods of metal degassing

Fig.2.21,

Filling

a mould in an autoclave s

1-

the

autoclave,

 

2-

the

hole

for pouring,

S4'

3-

the

lid j

 

 

4-

the

mould;

 

5-

valves.

 

 

Foundry Department

"Casting

defects and

Dr. V. Bastrakov.

measures of

their prevention”

Flushing with an inert gas is the most common tec­ hniques of gas removal* Inert gases such as chlorine , nitrogen, or argon arc widely used in practice. Chlorine, interacting with aluminium or ..;agnesium (this method is mainly used for degassing aluminium and magnesium alloys), forms gaseous AlCl^ or М^С12 neutral to the metal.

The gases are bubbled from graphite pipes directly throu­

gh the metal.

Due to the pressure of the dissolved

gas

( usually hydrogen ) within each inert gas bubble is

zero

any dissolved

gas migrates readily to the bubble where it

is collected

and taken out to the metal surface.

 

Last time solid degassers are also widely used for this purpose. For example, hoxahhlorinethane (C2 Clg) is used to give the flushing action to aluminium and. mag­ nesium alloys i

2 A1 + 3 CgClg

-----► ?C2C14

+ 2 A lC lj

(liqu id)(solid)

(gas)

(gas)

In steelmaking practice,

the

CO from the carbon boil

( FeO $ C - —» Fe

00

) acts as an inert

gas to flush

hydrogen from the metal.

However, taking into account the condition of the formation of a bubble from dissolved gases, according to

2- Measures improving quality of a mould.

The majority "blow boles is formed an a result of unsatisfactory quality of moulds or some deviations from a technological process of their production.

It should be noted that gas holes as a result of the unquality preparation of a mould especially often oc­ cur in cast iron and non-ferrous castings. Steel cast­ ings are subjected to such blow holes in a less degree,as

steel is poured with less overheating and the strong solid skin of the metal, preventing gases of the mould from the penetration into the casting, is formed very quickly at po­ uring the steel.

Shrinlaage cavities.

Shrinkage is one of the most important characteris­ tics of alloys which hardly influences on casting quality.

This is the property of metals and alloys to change their volume on solidification and cooling. In nearly a ll cases, solidification and cooling the casting are accoipanied by the reduction of its volume. Usually shrinkage occurs in three stages, in.the molten metal before solidifying(liquid contraction)} in solidifying ( solidification shrinkage )j and in the solid metal during cooling the metal upto room tenperatura ( solid contraction )•

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