Добавил:
Опубликованный материал нарушает ваши авторские права? Сообщите нам.
Вуз: Предмет: Файл:

n29fIAwxpY

.pdf
Скачиваний:
2
Добавлен:
15.04.2023
Размер:
18.9 Mб
Скачать

100%

90%

80%

70%

60%

50%

40%

30%

20%

10%

0%

Mon14Tynk(2) pt1

Mon14Tynk(2) pt2

Mon14Tynk(2) pt3

Mon14Tynk(2) pt4

Mon14Tynk(2) pt5

Mon14Tynk(2) pt6

Mon14Tynk(2) pt7

Mon14Tynk(2) pt8

Mon14Tynk(2) pt9

Mon14Tynk(2) pt10

Mon14Tynk(2) pt11

Mon14Tynk(2) pt12

Mon14Tynk(2) pt13

Mon14Tynk(2) pt14

Mon14Tynk(2) pt15

Mon14Tynk(2) pt16

Mon14Tynk(2) pt17

Mon14Tynk(2) pt18

Mon14Tynk(2) pt19

Mon14Tynk(2) pt20

Mon14Tynk(2) pt21

Mon14Tynk(2) pt22

Mon14Tynk(2) pt23

Mon14Tynk(2) pt24

Mon14Tynk(2) pt25

Zn-L

Fe-L

Ca-K

K-K

S-K

P-K

Si-K

Al-K

Mg-K

Na-K

F-K

O-K

N-K

Fig. 5.8. Graphs of chemical composition of metals in individual Monchegorsk plaster samples based on microscale studies

Tab. 5.1. The results of the Mon01 sample microanalysis

Sample

C

O

F

Na

Mg

Al

Si

P

S

K

Ca

Ti

Fe

Zn

Mon01(1)1

11.61

30.84

 

0.86

3.44

8.27

25.42

 

 

5.78

4.45

4.87

4.47

 

Mon01(1)2

5.27

40.52

 

 

4.88

7.34

15.84

 

 

4.61

1.88

2.41

17.25

 

Mon01(1)3

12.43

43.39

0.00

1.88

2.30

7.13

20.98

 

 

 

5.59

 

6.31

 

Mon01(1)4

10.31

47.33

0.34

4.17

1.34

8.65

22.14

 

 

0.70

3.26

1.77

 

 

Mon01(1)5

6.14

49.35

 

1.16

0.66

8.12

24.58

 

 

7.27

1.57

1.16

 

 

Mon01(1)6

10.85

45.10

 

0.90

1.70

5.00

14.89

 

 

1.47

17.40

2.71

 

 

Mon01(1)7

16.20

40.26

 

1.43

1.65

6.23

27.93

 

 

1.94

4.36

 

 

 

Mon01(1)8

14.85

37.61

 

1.03

2.13

7.18

22.28

 

 

4.20

5.98

 

4.74

 

Mon01(1)9

12.25

45.38

1.45

0.93

1.97

11.36

19.96

 

 

4.00

2.70

 

 

 

Mon01(1)10

10.29

46.38

1.20

3.27

1.74

8.73

22.80

 

 

1.48

4.12

 

 

 

Mon01(1)11

8.57

49.93

 

0.27

1.13

2.39

6.98

 

0.75

0.86

27.74

1.37

 

 

Mon01(1)12

11.04

38.98

 

2.68

1.74

10.46

26.74

 

 

2.14

6.22

 

 

 

Mon01(1)13

8.21

39.40

 

 

4.53

8.18

17.71

 

 

3.75

3.13

2.40

12.69

 

Mon01(1)14

13.28

41.48

0.54

1.43

2.08

5.92

18.94

 

 

1.78

9.89

4.65

 

 

Mon01(1)15

20.19

42.61

 

1.76

2.45

6.62

16.51

 

 

1.22

2.66

1.61

4.38

 

Mon01(1)16

17.89

42.70

0.42

1.23

2.41

5.46

19.44

1.56

 

1.95

4.45

2.48

 

 

Mon01(1)17

14.12

43.66

0.83

2.45

1.51

8.71

19.87

 

 

1.33

4.91

2.61

 

 

Mon01(1)18

10.00

38.46

 

1.11

3.84

3.95

20.56

 

 

0.91

11.70

2.01

7.48

 

Mon01(1)19

8.68

43.53

0.69

0.66

1.68

4.00

16.40

 

 

1.06

2.54

2.00

 

18.76

Mon01(1)20

18.27

43.46

1.46

1.56

2.15

6.95

18.01

 

 

2.04

3.72

2.39

 

 

Mon01(1)21

11.64

42.23

0.30

3.49

1.13

7.79

24.91

 

 

1.15

5.27

2.09

 

 

Mon01(1)22

13.42

45.38

 

1.39

1.85

5.81

20.29

 

 

1.87

5.33

4.67

 

 

Mon01(1)23

12.48

40.11

0.37

1.05

1.77

7.54

25.12

 

 

4.48

6.27

 

0.80

 

Mon01(1)24

15.40

42.59

 

1.05

2.27

6.75

20.36

 

 

5.26

6.32

 

 

 

Mon01(1)25

7.88

52.47

 

 

0.77

1.71

5.51

 

 

 

31.66

 

 

 

121

Tab. 5.2. The results of the Mon02 sample microanalysis

Sample

C

O

F

Na

Mg

Al

Si

S

K

Ca

Ti

Fe

Zn

Br

Mon02(1)1

4.17

26.24

0.85

0.56

1.31

1.09

3.44

9.98

 

12.41

 

39.95

 

 

Mon02(1)2

5.03

48.69

0.61

 

6.97

2.49

12.20

10.42

1.01

12.58

 

 

 

 

Mon02(1)3

6.86

41.61

 

1.51

3.38

3.72

13.21

8.19

1.47

20.03

 

 

 

 

Mon02(1)4

4.67

36.10

 

1.08

1.99

2.17

7.31

18.77

 

27.91

 

 

 

 

Mon02(1)5

5.47

45.05

 

 

7.10

3.93

14.85

7.23

1.23

7.69

 

4.66

2.79

 

Mon02(1)6

4.66

53.56

1.06

0.70

4.09

1.93

28.31

2.05

0.66

2.95

 

 

 

 

Mon02(1)7

9.78

48.16

0.51

 

1.30

1.05

3.55

15.10

0.46

20.08

 

 

 

 

Mon02(1)8

5.90

41.57

1.42

 

4.53

3.46

13.79

10.66

2.49

16.18

 

 

 

 

Mon02(1)9

3.79

45.66

 

 

2.35

1.17

5.39

17.54

 

24.10

 

 

 

 

Mon02(1)10

7.39

48.01

 

 

2.73

1.98

11.26

8.53

 

20.11

 

 

 

 

Mon02(1)12

6.60

38.53

 

0.56

2.21

 

6.34

14.59

 

28.85

 

 

 

2.32

Mon02(1)13

3.36

57.42

0.38

 

1.48

0.96

3.55

14.82

 

18.03

 

 

 

 

Mon02(1)14

3.13

30.72

 

 

0.92

0.66

2.37

3.19

 

4.53

7.18

47.30

 

 

Mon02(1)15

11.64

47.19

 

 

3.25

3.02

16.79

6.77

 

11.33

 

 

 

 

Mon02(1)16

8.26

45.44

 

 

2.60

3.83

12.86

6.00

 

21.02

 

 

 

 

Mon02(1)17

5.94

38.42

 

0.89

3.42

7.13

23.41

2.57

7.73

5.44

 

5.04

 

 

Mon02(1)18

6.32

48.88

0.28

 

5.17

3.11

14.04

8.73

1.17

10.10

 

 

2.21

 

Mon02(1)19

5.76

38.56

0.21

0.94

1.74

2.54

9.37

14.64

1.46

24.78

 

 

 

 

Mon02(1)20

9.71

47.77

0.92

1.52

3.69

4.55

14.65

4.54

 

12.65

 

 

 

 

Mon02(1)21

3.82

51.07

 

 

2.76

1.89

5.84

15.77

 

18.85

 

 

 

 

Mon02(1)22

6.40

45.71

1.81

 

3.09

6.06

15.82

7.39

 

13.71

 

 

 

 

Mon02(1)23

4.76

48.31

 

0.54

4.26

3.92

14.40

10.56

 

13.25

 

 

 

 

Mon02(1)24

10.47

44.93

 

 

3.44

2.28

10.53

6.88

 

21.48

 

 

 

 

Mon02(1)25

9.85

40.89

 

 

3.34

1.43

7.99

12.24

 

24.25

 

 

 

 

Tab. 5.3. The results of the Mon03 sample microanalysis

Sample

C

N

O

F

Na

Mg

Al

Si

S

K

Ca

Ti

Fe

Zn

Br

Ba

Mon03(1)1

3.16

 

30.22

 

1.75

1.31

3.55

10.98

7.96

 

3.14

 

 

 

 

37.92

Mon03(1)2

30.42

8.36

42.56

 

1.46

1.74

1.11

8.03

 

 

6.31

 

 

 

 

 

Mon03(1)3

17.54

 

48.03

 

 

 

 

20.05

 

 

 

 

14.38

 

 

 

Mon03(1)4

10.39

 

54.80

 

 

 

 

15.38

 

 

19.43

 

 

 

 

 

Mon03(1)5

10.70

 

50.17

 

 

 

6.36

15.51

 

 

17.26

 

 

 

 

 

Mon03(1)6

11.63

 

50.89

 

 

2.67

5.05

16.48

 

 

13.28

 

 

 

 

 

Mon03(1)7

12.22

 

52.78

 

 

 

4.90

16.01

 

 

14.08

 

 

 

 

 

Mon03(1)8

7.36

 

48.89

 

 

2.00

6.10

25.43

 

 

10.22

 

 

 

 

 

Mon03(1)9

10.87

 

42.95

 

1.75

 

5.48

24.19

 

 

14.75

 

 

 

 

 

Mon03(1)10

6.03

 

52.09

0.87

1.31

1.74

2.57

28.84

 

 

6.54

 

 

 

 

 

Mon03(1)11

3.76

 

36.44

 

3.15

1.92

5.41

15.29

 

 

4.94

 

29.11

 

 

 

Mon03(1)12

8.30

 

52.32

2.35

 

2.15

6.57

21.25

 

 

7.07

 

 

 

 

 

Mon03(1)13

6.38

 

36.02

 

 

2.61

4.65

17.18

 

 

9.86

7.34

12.39

3.56

 

 

Mon03(1)14

9.01

 

44.66

 

 

1.99

2.85

10.54

 

 

25.10

 

5.86

 

 

 

Mon03(1)15

9.27

 

46.02

 

 

 

4.44

14.98

 

 

25.30

 

 

 

 

 

Mon03(1)16

9.40

 

48.83

 

 

3.37

5.85

16.99

 

 

15.57

 

 

 

 

 

Mon03(1)17

10.33

 

47.22

 

 

2.30

5.31

18.39

 

 

16.45

 

 

 

 

 

Mon03(1)18

7.71

 

52.30

2.63

 

2.12

6.18

23.35

 

 

5.71

 

 

 

 

 

Mon03(1)19

4.93

 

49.31

1.62

 

3.00

3.88

14.76

 

 

22.50

 

 

 

 

 

Mon03(1)20

8.09

 

49.56

0.48

 

1.71

 

13.43

 

 

18.91

 

 

 

7.82

 

Mon03(1)21

4.06

 

39.69

0.19

 

1.40

1.90

6.27

 

 

46.48

 

 

 

 

 

Mon03(1)22

5.67

 

49.55

 

 

1.52

2.16

9.03

 

 

32.08

 

 

 

 

 

Mon03(1)23

5.14

 

39.34

 

 

1.87

2.27

6.97

 

 

44.42

 

 

 

 

 

Mon03(1)24

3.79

 

40.84

 

 

1.63

8.11

6.97

 

 

20.52

 

18.15

 

 

 

Mon03(1)25

8.96

 

46.73

 

 

2.96

4.16

23.68

 

2.22

11.29

 

 

 

 

 

122

Tab. 5.4. The results of the Mon05 sample microanalysis

Sample

C

N

O

Na

Mg

Al

Si

S

K

Ca

Ti

Fe

Ni

Br

Mon05(1)1

6.97

 

40.56

0.88

1.41

4.26

13.06

 

 

5.03

 

27.82

 

 

Mon05(1)2

10.76

 

33.70

 

 

 

3.35

 

 

5.34

 

46.85

 

 

Mon05(1)3

29.66

 

48.01

 

 

1.29

4.60

 

 

16.44

 

 

 

 

Mon05(1)4

7.80

 

37.58

 

1.25

2.30

5.42

 

 

45.65

 

 

 

 

Mon05(1)5

49.79

 

30.53

 

0.99

1.85

6.21

3.04

 

7.60

 

 

 

 

Mon05(1)6

31.19

9.25

42.90

0.87

1.24

2.07

6.34

 

 

6.14

 

 

 

 

Mon05(1)7

15.01

 

45.33

 

 

2.99

9.13

 

 

27.55

 

 

 

 

Mon05(1)8

22.46

 

47.48

 

1.33

2.85

10.07

 

 

15.80

 

 

 

 

Mon05(1)9

14.55

 

40.22

 

1.72

3.30

16.95

 

 

23.27

 

 

 

 

Mon05(1)10

7.28

 

37.90

 

0.97

2.17

8.82

 

 

42.86

 

 

 

 

Mon05(1)11

7.45

 

40.62

 

1.69

3.31

11.56

 

 

35.38

 

 

 

 

Mon05(1)12

6.98

 

45.91

 

3.03

2.76

8.96

 

 

32.36

 

 

 

 

Mon05(1)13

22.90

 

51.52

 

1.42

2.90

8.72

 

 

12.54

 

 

 

 

Mon05(1)14

6.41

 

41.89

 

 

 

7.19

 

 

44.51

 

 

 

 

Mon05(1)15

12.50

 

44.30

 

1.05

4.87

17.45

 

 

19.83

 

 

 

 

Mon05(1)16

12.59

 

49.06

0.60

1.39

3.52

10.69

 

1.04

8.31

3.98

 

8.82

 

Mon05(1)17

12.24

 

43.10

 

 

 

15.57

 

 

19.58

 

4.54

 

4.97

Mon05(1)18

11.52

 

45.60

 

1.78

3.16

15.59

 

 

22.34

 

 

 

 

Mon05(1)19

12.21

 

38.68

 

2.00

4.71

17.82

 

 

20.66

 

3.91

 

 

Mon05(1)20

4.67

 

49.68

 

5.32

4.55

16.00

 

 

19.78

 

 

 

 

Mon05(1)21

6.81

 

49.76

 

 

2.19

8.34

 

 

32.89

 

 

 

 

Mon05(1)22

5.71

 

40.23

 

3.53

4.28

19.99

 

 

26.27

 

 

 

 

Mon05(1)23

10.76

 

36.48

 

1.80

5.08

20.55

 

 

23.57

 

1.76

 

 

Mon05(1)24

11.65

 

39.72

 

1.27

4.34

15.24

 

4.74

23.05

 

 

 

 

Mon05(1)25

5.55

 

30.30

 

1.20

2.65

10.70

 

 

43.23

6.37

 

 

 

Tab. 5.5. The results of the Mon07 sample microanalysis

Sample

C

N

O

F

Na

Mg

Al

Si

P

S

K

Ca

Ti

Fe

Ni

Br

Mon07(1)1

25.63

 

42.71

 

 

2.73

 

13.84

 

 

4.40

10.69

 

 

 

 

Mon07(1)2

14.37

 

30.19

 

 

1.87

2.60

11.39

 

 

4.00

9.99

25.60

 

 

 

Mon07(1)3

10.35

 

39.31

 

 

3.77

8.99

16.80

 

 

5.18

2.48

 

13.11

 

 

Mon07(1)4

20.94

 

37.40

 

 

11.20

7.29

16.33

 

 

 

3.42

3.43

 

 

 

Mon07(1)5

26.31

 

40.28

 

 

3.69

1.77

6.06

 

 

 

16.18

5.72

 

 

 

Mon07(1)6

10.17

 

31.78

 

 

0.99

 

6.81

 

 

 

2.77

 

 

47.48

 

Mon07(1)7

23.85

7.12

47.55

2.50

 

0.99

3.47

10.06

 

1.01

 

3.45

 

 

 

 

Mon07(1)8

33.57

11.40

43.95

 

 

0.73

1.20

5.22

 

 

 

3.94

 

 

 

 

Mon07(1)9

13.30

 

33.72

 

 

 

 

19.38

 

 

 

10.68

15.99

 

 

6.93

Mon07(1)10

34.88

11.93

39.24

 

 

 

1.23

5.20

 

 

 

7.52

 

 

 

 

Mon07(1)11

33.97

 

35.06

 

 

2.02

3.90

17.06

 

 

 

7.99

 

 

 

 

Mon07(1)12

14.48

 

32.36

 

 

1.20

2.31

5.90

2.90

 

 

28.33

12.52

 

 

 

Mon07(1)13

30.11

 

33.65

 

 

1.78

2.30

12.71

3.17

 

 

8.66

7.62

 

 

 

Mon07(1)14

22.66

 

46.81

 

 

1.66

3.74

16.36

 

 

 

6.46

2.31

 

 

 

Mon07(1)15

28.03

 

44.82

 

 

 

3.21

12.83

 

 

 

11.10

 

 

 

 

Mon07(2)1

13.48

 

13.11

12.83

 

 

1.41

4.74

 

25.58

 

 

 

 

28.84

 

Mon07(2)2

14.58

 

38.21

 

 

2.21

2.75

18.59

 

 

 

8.09

15.58

 

 

 

Mon07(2)3

13.01

 

35.31

 

 

2.56

2.94

13.81

 

 

 

27.84

4.52

 

 

 

Mon07(2)4

29.27

 

39.73

1.31

1.20

1.91

3.28

15.77

 

 

 

7.53

 

 

 

 

Mon07(2)5

23.92

 

43.25

 

 

 

2.82

19.16

 

 

1.09

3.59

6.17

 

 

 

Mon07(2)6

18.25

 

49.04

0.79

1.09

2.35

4.29

12.20

3.16

 

 

8.83

 

 

 

 

Mon07(2)7

9.87

 

42.85

 

 

0.74

0.91

7.04

 

 

 

18.45

20.14

 

 

 

Mon07(2)8

10.53

 

48.92

 

 

2.61

2.72

20.28

 

 

 

6.32

8.63

 

 

 

Mon07(2)9

26.30

 

40.88

 

 

1.76

 

12.67

 

 

 

5.99

6.35

 

 

6.05

Mon07(2)10

14.52

 

49.44

 

 

4.31

2.04

13.53

 

 

 

9.61

6.55

 

 

 

Mon07(2)11

9.50

 

52.17

 

0.46

1.27

2.96

20.37

 

 

 

6.34

6.93

 

 

 

Mon07(2)12

26.75

10.12

39.00

 

 

1.09

2.29

11.24

 

1.39

 

4.25

3.87

 

 

 

Mon07(2)13

23.08

 

45.10

1.94

 

3.63

5.40

13.94

 

 

 

6.91

 

 

 

 

Mon07(2)14

11.10

 

48.11

2.52

 

6.42

7.56

16.25

 

 

3.53

4.51

 

 

 

 

Mon07(2)15

18.36

 

33.43

 

 

 

 

24.89

 

 

 

5.74

8.97

3.72

 

4.89

123

Tab. 5.6. The results of the Mon08 sample microanalysis

Sample

C

N

O

F

Na

Mg

Al

Si

P

S

Cl

K

Ca

Fe

Br

Mon08(1)1

5.66

 

27.25

 

 

 

 

1.45

 

 

 

 

1.57

64.08

 

Mon08(1)2

27.51

 

40.78

 

 

1.82

 

6.91

 

1.54

 

 

19.32

 

2.12

Mon08(1)3

43.51

 

42.37

 

1.72

 

 

2.41

 

 

2.70

 

7.30

 

 

Mon08(1)4

18.56

 

42.57

 

0.92

4.87

7.56

16.48

 

 

 

4.10

4.94

 

 

Mon08(1)5

18.31

 

48.62

 

 

 

1.20

2.07

 

 

 

 

29.81

 

 

Mon08(2)1

7.66

 

48.78

4.28

 

 

 

 

12.89

 

 

 

26.39

 

 

Mon08(2)2

19.85

 

55.20

2.44

 

1.71

2.58

5.52

 

 

 

1.49

11.22

 

 

Mon08(2)3

7.12

 

29.04

 

 

 

 

1.52

 

1.18

 

 

2.47

58.68

 

Mon08(2)4

17.01

 

52.44

 

 

 

2.54

8.36

 

 

 

 

19.66

 

 

Mon08(2)5

17.68

 

42.01

1.40

0.73

4.46

2.87

13.09

 

 

 

 

17.76

 

 

Mon08(2)6

31.78

 

51.54

3.17

 

 

 

2.34

 

 

1.78

 

9.39

 

 

Mon08(2)7

42.96

 

48.59

 

 

 

 

1.65

 

 

 

2.01

4.78

 

 

Mon08(2)8

15.32

 

47.11

 

 

 

 

2.92

 

 

 

 

34.64

 

 

Mon08(2)9

10.84

 

46.69

4.03

 

6.63

7.64

14.84

 

 

 

4.89

4.45

 

 

Mon08(2)10

8.70

 

48.71

8.99

 

5.71

7.01

13.31

 

 

 

5.16

2.41

 

 

Mon08(2)11

17.07

 

58.72

 

 

 

 

2.10

 

 

 

 

22.10

 

 

Mon08(2)12

27.11

 

52.37

 

 

0.89

1.63

15.66

 

 

 

 

2.35

 

 

Mon08(2)13

8.76

 

42.13

 

 

 

2.57

6.60

 

2.11

 

 

4.67

33.17

 

Mon08(2)14

14.95

 

42.80

 

 

 

 

6.09

 

 

 

 

36.17

 

 

Mon08(2)15

35.48

16.45

39.80

 

0.65

0.86

 

2.13

 

 

0.94

 

3.71

 

 

Mon08(3)1

8.62

 

50.81

2.35

 

1.42

9.30

22.18

 

 

 

1.65

3.69

 

 

Mon08(3)2

4.28

 

30.41

 

 

2.03

1.99

4.56

 

 

 

 

 

56.74

 

Mon08(3)3

4.28

 

28.49

 

 

 

1.62

3.11

 

 

 

 

1.65

60.86

 

Mon08(3)4

5.68

 

33.86

 

 

1.06

1.50

4.16

 

 

 

 

2.05

51.69

 

Mon08(3)5

10.38

 

38.47

 

2.35

1.46

6.20

16.89

 

 

 

 

 

24.25

 

Mon08(3)6

6.17

 

34.21

 

 

4.64

1.46

8.14

 

 

 

 

1.75

43.64

 

Mon08(3)7

14.92

 

58.69

 

 

 

 

2.36

 

 

 

 

22.50

 

1.53

Mon08(3)8

12.77

 

60.15

 

 

 

 

1.73

 

 

 

 

25.35

 

 

Mon08(3)9

10.96

 

56.04

 

 

 

1.31

4.63

 

 

 

 

27.07

 

 

Mon08(3)10

11.13

 

48.35

 

 

 

0.88

1.87

 

 

 

 

37.77

 

 

Mon08(3)11

9.11

 

54.67

4.93

 

1.38

4.42

12.79

 

 

 

 

12.71

 

 

Mon08(3)12

31.38

5.71

51.36

 

 

0.93

1.95

6.40

 

 

 

 

2.27

 

 

Mon08(3)13

29.48

 

48.11

 

 

 

3.19

9.21

 

 

 

3.35

6.67

 

 

Tab. 5.7. The results of the Mon09 sample microanalysis

Sample

C

N

O

F

Na

Mg

Al

Si

K

Ca

Fe

As

Br

Mon09(1)1

11.57

 

49.78

1.44

 

1.50

6.46

18.40

 

10.85

 

 

 

Mon09(1)2

18.95

 

44.18

 

 

1.85

3.94

12.92

 

18.15

 

 

 

Mon09(1)3

7.27

 

50.73

0.04

 

1.43

7.21

17.82

 

15.50

 

 

 

Mon09(1)4

9.38

 

50.42

2.47

 

 

10.27

10.29

 

17.17

 

 

 

Mon09(1)5

20.18

7.25

49.11

0.28

 

1.31

1.77

10.92

 

9.18

 

 

 

Mon09(1)6

8.73

 

43.17

1.11

0.42

2.30

2.36

12.11

 

29.80

 

 

 

Mon09(1)7

9.36

 

56.02

 

 

1.06

1.48

6.01

0.78

25.30

 

 

 

Mon09(1)8

10.15

 

48.68

 

 

0.96

2.81

9.79

1.38

26.22

 

 

 

Mon09(1)9

6.30

 

36.74

 

 

2.39

11.38

9.98

 

26.61

6.59

 

 

Mon09(1)10

9.23

 

36.93

 

 

2.13

4.71

18.33

 

28.67

 

 

 

Mon09(1)11

11.30

 

41.81

 

 

 

3.33

8.86

 

34.71

 

 

 

Mon09(1)12

9.78

 

50.99

 

 

7.39

1.43

5.21

 

25.20

 

 

 

Mon09(1)13

17.89

 

37.78

 

0.95

1.82

4.98

23.46

 

11.14

1.99

 

 

Mon09(1)14

23.53

 

43.27

 

 

1.22

 

10.38

 

15.48

 

 

6.12

Mon09(1)15

6.58

 

44.77

4.97

 

1.60

9.20

6.58

 

26.31

 

 

 

Mon09(1)16

17.65

 

39.28

0.73

 

1.65

 

11.32

 

22.67

 

 

6.69

Mon09(1)17

10.78

 

37.35

 

 

 

2.46

7.56

 

41.86

 

 

 

Mon09(1)18

16.57

 

37.85

 

 

2.13

3.17

15.60

 

24.67

 

 

 

Mon09(1)19

10.18

 

52.06

 

 

0.97

1.01

4.80

 

30.98

 

 

 

Mon09(1)20

14.63

 

39.96

2.25

 

1.78

2.95

11.82

 

26.61

 

 

 

124

Mon09(1)21

9.13

 

48.00

 

0.85

2.18

8.62

15.44

 

15.77

 

 

 

Mon09(1)22

8.43

 

48.91

1.58

 

 

11.16

15.17

 

13.89

 

0.86

 

Mon09(1)23

9.47

 

49.78

 

 

0.61

1.23

32.75

 

6.16

 

 

 

Mon09(1)24

20.03

 

38.53

 

0.70

2.78

3.77

28.20

 

5.99

 

 

 

Mon09(1)25

8.21

 

49.60

 

 

2.79

4.84

24.18

 

10.38

 

 

 

Tab. 5.8. The results of the Mon10 sample microanalysis

Sample

C

O

Na

Mg

Al

Si

S

Cl

Ca

Fe

Zn

Ba

Pb

Mon10(1)1

2.96

44.21

 

 

1.01

15.01

3.06

 

27.82

 

5.92

 

 

Mon10(1)2

2.81

43.83

 

 

 

4.12

18.06

 

25.53

 

5.64

 

 

Mon10(1)3

3.83

23.94

 

 

 

5.18

 

 

4.08

 

62.97

 

 

Mon10(1)4

7.22

30.60

 

 

 

8.02

1.96

1.40

16.06

 

34.74

 

 

Mon10(1)5

7.32

31.89

 

 

 

5.03

2.51

2.85

14.01

 

36.40

 

 

Mon10(1)6

2.35

24.36

 

 

 

6.91

14.07

 

4.91

 

5.40

42.01

 

Mon10(1)7

6.21

41.69

 

 

 

5.81

2.84

1.85

22.18

 

19.41

 

 

Mon10(1)8

6.46

34.70

 

 

 

5.60

3.93

0.79

12.70

 

35.82

 

 

Mon10(1)9

5.19

37.81

 

 

 

9.91

7.72

2.47

26.33

 

10.58

 

 

Mon10(1)10

5.81

34.90

 

 

 

5.92

2.61

1.86

14.74

 

34.15

 

 

Mon10(1)11

4.56

40.08

 

 

 

6.09

 

 

37.89

 

11.39

 

 

Mon10(1)12

7.56

49.67

 

 

 

4.23

2.00

1.32

27.31

 

7.91

 

 

Mon10(1)13

4.58

42.36

 

 

 

9.97

 

3.67

23.06

 

16.35

 

 

Mon10(1)14

3.96

36.68

 

 

 

6.96

2.50

1.51

32.22

 

16.16

 

 

Mon10(1)15

5.56

32.97

 

 

 

7.62

3.70

2.43

10.82

 

36.90

 

 

Mon10(1)16

5.30

54.83

 

 

 

7.33

10.63

 

21.92

 

 

 

 

Mon10(1)17

5.39

44.54

 

 

 

12.53

3.19

 

28.12

 

6.23

 

 

Mon10(1)18

4.35

48.19

 

0.74

1.79

24.43

1.41

 

10.71

 

8.39

 

 

Mon10(1)19

5.83

49.49

 

1.08

3.43

18.08

1.00

 

12.73

 

8.37

 

 

Mon10(1)20

4.37

47.49

 

 

 

15.35

1.52

 

27.02

 

4.24

 

 

Mon10(1)21

4.27

39.03

 

 

0.72

13.14

2.20

 

35.17

 

5.47

 

 

Mon10(1)22

4.32

46.85

4.08

0.91

1.38

16.32

 

 

26.14

 

 

 

 

Mon10(1)23

3.20

52.88

 

0.48

 

11.03

11.78

 

15.39

 

5.25

 

 

Mon10(1)24

2.82

45.65

5.33

 

7.78

28.39

2.77

 

7.27

 

 

 

 

Mon10(1)25

2.10

37.79

 

 

 

14.22

0.98

 

2.25

30.92

10.79

 

0.94

Tab. 5.9. The results of the Mon11 sample microanalysis

Sample

C

N

O

F

Na

Mg

Al

Si

S

K

Ca

Br

Mon11(2)1

13.13

4.65

37.19

1.44

1.54

4.13

3.02

9.77

 

 

25.14

 

Mon11(2)2

7.42

 

52.96

 

 

0.58

 

2.36

 

 

36.66

 

Mon11(2)3

4.16

 

27.40

 

 

0.68

 

3.11

 

 

64.65

 

Mon11(2)4

21.82

 

42.81

 

 

1.70

 

7.65

 

 

26.02

 

Mon11(2)5

18.60

 

41.12

 

 

 

 

8.57

 

 

31.71

 

Mon11(2)6

4.72

 

32.07

 

 

 

 

3.18

 

 

60.03

 

Mon11(2)7

10.64

 

51.06

 

 

3.75

 

8.64

 

 

25.91

 

Mon11(2)8

3.23

 

28.16

 

 

1.26

 

2.80

 

 

64.55

 

Mon11(2)9

3.51

 

29.69

 

 

 

 

6.78

 

 

60.02

 

Mon11(2)10

17.06

 

54.44

 

 

 

 

 

 

 

28.50

 

Mon11(2)11

15.20

 

50.01

 

 

 

 

 

 

 

34.80

 

Mon11(2)12

22.16

 

34.36

 

 

 

 

10.02

 

 

25.86

7.62

Mon11(2)13

30.25

12.47

37.07

 

 

 

1.48

3.68

 

 

15.06

 

Mon11(2)14

6.64

 

51.86

 

 

 

0.70

2.92

1.61

 

36.27

 

Mon11(2)15

12.69

 

44.83

 

 

 

 

4.78

 

 

37.71

 

Mon11(2)16

11.01

 

46.93

 

 

 

 

6.84

 

 

35.22

 

Mon11(2)17

12.38

 

48.66

 

 

 

 

14.14

 

 

24.83

 

Mon11(2)18

6.16

 

51.48

 

0.68

1.17

 

3.63

 

1.02

35.85

 

Mon11(2)19

22.15

 

38.21

 

 

5.48

4.00

11.27

4.45

 

14.44

 

Mon11(2)20

5.05

 

32.49

 

 

 

 

5.24

 

 

57.22

 

Mon11(2)21

6.39

 

56.51

 

 

0.89

 

4.03

 

 

32.19

 

Mon11(2)22

5.38

 

40.90

 

 

1.15

1.58

5.40

 

 

45.58

 

125

Tab. 5.10. The results of the Mon12 sample microanalysis

Sample

C

O

F

Mg

Al

Si

S

K

Ca

Fe

Zn

Mon12(1)1

6.76

33.51

 

 

 

2.10

 

 

30.45

27.18

 

Mon12(1)2

6.33

34.40

 

 

 

3.81

 

 

14.43

41.02

 

Mon12(1)3

5.11

34.16

 

 

 

1.95

 

 

2.69

56.09

 

Mon12(1)4

8.96

58.14

1.86

 

0.43

1.59

 

 

29.03

 

 

Mon12(1)5

7.17

32.11

 

 

 

2.02

 

 

12.29

41.93

4.48

Mon12(1)6

10.79

44.46

 

1.65

1.79

4.83

 

1.09

20.00

15.40

 

Mon12(1)7

6.60

42.23

 

 

 

 

 

 

29.57

21.60

 

Mon12(1)8

7.63

49.11

7.89

 

 

 

 

 

35.37

 

 

Mon12(1)9

4.80

45.41

0.90

 

 

3.49

 

 

35.80

9.61

 

Mon12(1)10

6.47

33.16

 

 

 

3.36

 

 

24.02

32.99

 

Mon12(1)11

6.27

34.02

 

 

 

 

 

 

7.64

52.07

 

Mon12(1)12

4.92

36.41

 

 

 

 

 

 

8.29

50.38

 

Mon12(1)13

8.48

36.46

 

 

 

2.83

 

 

13.24

39.00

 

Mon12(1)14

3.60

35.88

1.63

 

 

 

 

 

31.83

27.06

 

Mon12(1)15

5.67

47.01

 

 

 

2.64

 

 

44.69

 

 

Mon12(1)16

7.68

39.30

 

 

 

4.25

 

 

19.01

29.75

 

Mon12(1)17

6.26

35.74

 

 

 

2.58

 

 

 

55.42

 

Mon12(1)18

3.68

35.65

 

 

 

1.90

 

 

37.39

21.38

 

Mon12(1)19

6.87

35.38

 

 

 

2.81

 

 

11.40

43.53

 

Mon12(1)20

8.71

31.42

 

 

 

2.50

0.76

 

4.12

52.49

 

Mon12(1)21

6.55

33.22

 

 

 

1.38

 

 

5.14

53.71

 

Mon12(1)22

5.76

33.74

 

 

 

1.36

 

 

6.88

52.26

 

Mon12(1)23

6.80

40.61

 

1.77

 

 

 

 

22.45

28.39

 

Mon12(1)24

6.35

36.01

 

1.16

 

11.46

 

 

16.28

28.74

 

Mon12(1)25

6.75

38.02

3.56

 

 

4.67

 

 

7.63

39.37

 

Tab. 5.11. The results of the Mon13 sample microanalysis

Sample

C

O

F

Na

Mg

Al

Si

S

Cl

K

Ca

Fe

Zn

Ba

Pm

Mon13(1)1

4.54

27.57

 

1.91

 

3.81

7.51

9.39

5.01

3.02

 

 

 

37.24

 

Mon13(1)2

3.06

32.89

 

 

 

 

1.11

 

0.99

 

3.25

58.70

 

 

 

Mon13(1)3

8.66

47.91

3.51

3.67

 

6.61

16.43

 

4.50

 

8.71

 

 

 

 

Mon13(1)4

11.63

35.81

 

 

 

4.02

16.62

4.21

18.02

4.48

3.92

 

 

 

1.29

Mon13(1)5

9.66

19.59

 

1.25

 

 

3.67

7.66

7.14

 

7.38

7.46

 

36.19

 

Mon13(1)6

13.18

31.64

 

2.39

 

 

6.41

9.69

25.08

 

11.61

 

 

 

 

Mon13(1)7

5.16

53.35

 

1.18

 

 

1.45

15.41

5.42

 

18.04

 

 

 

 

Mon13(1)8

25.13

35.11

1.38

5.90

2.85

 

7.03

 

19.96

 

2.64

 

 

 

 

Mon13(1)9

22.33

40.77

 

 

3.23

 

7.79

 

13.04

 

12.84

 

 

 

 

Mon13(1)10

7.17

43.14

 

1.56

 

0.91

7.62

16.75

2.46

 

20.39

 

 

 

 

Mon13(1)11

23.99

29.01

 

1.86

5.84

 

20.45

 

18.85

 

 

 

 

 

 

Mon13(1)12

5.49

49.57

 

2.66

 

 

2.61

17.01

1.40

 

21.27

 

 

 

 

Mon13(1)13

5.20

35.09

 

 

0.00

0.89

8.60

7.34

5.83

1.10

4.43

 

 

23.46

8.06

Mon13(1)14

4.68

30.60

 

 

0.66

 

2.56

2.66

2.93

 

55.91

 

 

 

 

Mon13(1)15

25.16

36.91

 

 

 

 

5.55

 

20.02

 

12.35

 

 

 

 

Mon13(1)16

14.35

28.68

0.73

 

1.25

4.49

5.76

 

31.83

 

4.15

 

8.76

 

 

Mon13(1)17

17.36

37.44

 

 

 

1.55

24.81

 

7.89

 

8.97

 

 

 

1.98

Mon13(1)18

6.48

42.14

0.93

2.29

6.32

4.67

14.52

3.86

5.04

6.62

7.13

 

 

 

 

Mon13(1)19

9.76

42.84

 

 

 

2.08

32.05

2.69

5.35

 

5.23

 

 

 

 

Mon13(1)20

12.64

26.21

 

1.83

 

 

7.61

11.25

6.77

 

33.68

 

 

 

 

Mon13(1)21

15.11

34.48

 

 

 

 

6.71

5.55

13.35

 

12.08

 

 

 

12.72

Mon13(1)22

18.52

26.48

 

2.23

11.61

 

23.46

 

13.45

 

4.25

 

 

 

 

Mon13(1)23

4.21

40.08

 

1.40

6.67

7.69

14.81

 

4.21

6.49

2.43

12.02

 

 

 

Mon13(1)24

20.52

46.47

 

 

 

 

8.51

 

14.64

 

9.86

 

 

 

 

Mon13(1)25

28.68

37.38

 

 

 

 

 

 

21.55

 

12.39

 

 

 

 

126

Tab. 5.12. The results of the Mon14 sample microanalysis

Sample

C

N

O

F

Na

Mg

Al

Si

P

S

K

Ca

Fe

Zn

Pm

Mon14(2)1

14.20

 

51.24

 

 

 

3.71

24.46

 

 

 

6.39

 

 

 

Mon14(2)2

12.15

 

42.08

1.23

 

1.14

3.35

23.05

1.13

 

 

15.87

 

 

 

Mon14(2)3

5.60

 

45.47

 

 

 

4.10

24.88

 

 

 

4.77

15.19

 

 

Mon14(2)4

11.03

 

44.09

 

 

1.35

3.82

29.34

 

 

 

10.37

 

 

 

Mon14(2)5

11.76

 

46.51

0.77

 

0.56

1.58

20.48

 

1.09

 

8.72

 

8.55

 

Mon14(2)6

4.87

 

49.81

0.25

 

1.32

3.03

23.52

 

 

 

6.84

 

10.36

 

Mon14(2)7

4.77

 

46.64

 

 

0.76

2.32

27.56

 

1.76

 

7.98

 

8.21

 

Mon14(2)8

12.69

 

49.68

2.01

 

1.28

3.72

23.92

 

1.19

 

5.50

 

 

 

Mon14(2)9

15.35

 

46.97

 

 

 

2.77

28.86

 

 

 

6.06

 

 

 

Mon14(2)10

5.25

 

52.70

3.11

 

2.67

8.11

21.06

 

 

3.64

3.46

 

 

 

Mon14(2)11

4.13

 

48.06

 

 

 

2.70

26.54

 

 

 

2.21

10.51

5.85

 

Mon14(2)12

3.17

 

41.71

 

 

3.36

5.49

19.82

 

 

 

4.79

18.77

2.90

 

Mon14(2)13

5.85

 

51.43

2.83

1.63

 

5.00

29.15

 

 

 

4.10

 

 

 

Mon14(2)14

43.00

 

41.58

 

 

 

 

11.49

 

 

 

3.93

 

 

 

Mon14(2)15

15.41

 

52.40

 

 

 

 

32.19

 

 

 

 

 

 

 

Mon14(2)16

4.21

 

53.72

5.28

 

3.76

8.55

22.50

 

 

 

1.98

 

 

 

Mon14(2)17

3.42

1.42

50.89

 

6.02

 

8.96

26.52

 

 

 

2.77

 

 

 

Mon14(2)18

9.20

 

52.20

 

 

 

3.38

28.67

 

2.19

 

4.37

 

 

 

Mon14(2)19

10.59

 

40.84

 

 

 

2.69

34.45

 

 

 

11.44

 

 

 

Mon14(2)20

10.56

 

46.89

 

 

 

 

29.95

 

 

 

12.60

 

 

0.00

Mon14(2)21

8.64

 

47.91

 

 

 

2.77

22.13

 

 

 

8.47

 

10.08

 

Mon14(2)22

6.04

 

51.77

0.84

 

1.55

4.19

30.70

 

 

 

4.91

 

 

 

Mon14(2)23

7.44

 

52.27

1.13

 

1.16

3.55

31.30

 

 

 

3.16

 

 

 

Mon14(2)24

12.10

 

49.10

1.62

 

 

3.09

31.19

 

 

 

2.90

 

 

 

Mon14(2)25

18.63

 

43.49

 

 

 

 

32.87

 

 

 

5.01

 

 

 

127

6. Kandalaksha

6.1. Introduction

The town of Kandlaksz is situated in the south of the Košice peninsula on the White Sea. Owing to its location near the city, there are important international road and rail connections. Due to this fact, there are factories connected with railway rolling stock and port development, situated on the shore of the White Sea. This city is historically connected with the sea which in the old days was the only transport and communication road of this region. Archeological research shows that in the near distance of the city there are stone labyrinths of stone age (about 2ty B.C.). The first church was erected here in 1526. There is also a close documented ethnographic link between the Kandalaks and the Karens who inhabited the city and nearby Kolivica. The settlement has existed since the 11th century. In XIII century. She was attached to the Republic of Novgorod and since the 15th century. To the Grand Duchy of Moscow. At that time, the main connections of the city took place by sea from Archangelsk and further along the coast of the Baltic Sea. Kola, where the penetration of the region and the establishment of towns such as Umba, Warzuga and others. This situation changed at the beginning of the twentieth century, when a railway line connecting Murmansk with St. Petersburg was built. St. Petersburg, which runs in the neighborhood of the city. This has contributed to the development of the Candidates and its industry mainly focused on railways, ports and non-ferrous metals (mainly aluminum). The city was granted city rights in 1938 and now has nearly fifty thousand inhabitants. At that time, the city was also administratively attached to Murmansk Oblasti (formerly within the borders of the Republic of Karelia). It is also worth noting that in 1934, on the Niwa River, the first hydroelectric power plant was built on the Niwa.

The exact center of the city is built with the participation of wooden houses which are accompanied by neoclassic style brick buildings. These houses are located along the main arteries of the city. It is also surrounded by numerous blocks built of large plates. There are also some investments started in the 21st century, though their quantity is small.

City attractions are located in the eastern part of the White Sea Maze in (around 2000 BC), the Waterfalls of Kolwica, as well as two museums

The city’s climate is greatly mitigated by the presence of the White Sea. While the sea is winter it freezes (as opposed to the north of the Kołobrzeg Lagoon in Murmansk). This results in much greater continentalism of the climate. The White Sea, however, influences much higher humidity and more frequent precipitation in the summer. Summer in Canada is very short and winter is colder than in Murmansk, although the snowfall is much smaller (especially when the White Sea freezes). Spring comes only at the end of April

128

and winter starts in October. The average January temperature is –12´C and the summer is +14´C. However, a slightly more southern location of the city makes the height of trees is much higher than in Murmansk. In the neighborhood of the city pine appear up to 10m high. Also nearby is the Kandalakshaves Tundra – the hills are overgrown with forest passing rapidly into the forest and the tundra in the peaks of the mountains. On the shortest day of the year the sun shines one hour and 13 minutes and the polar day occurs between June 2 and July 11.

6.2. Methodology

Plaster samples were taken in the field. Plaster inventory and photographic documentation were also performed (fig. 6.7). These samples were then examined by microscopic methods and subsequently by scanning electron microscope. Chemical research was done by ICP-OAS and ASA. These results have been developed mathematically.

6.3. Results of the study

Field studies have shown that in the strict center the buildings are generally well preserved. There are, however, changes due to weathering of buildings and frost characteristic for all cities in the region (fig. 6.5). In general, however, there are maintenance works carried out in the city to reduce such zones. Neighborhood blocks, as in other towns in the region, are generally well preserved, but like in other cases they lack color and warmth.

6

5

4

3

2

1

0

KK01

KK02

 

KK03

KK04

KK05

 

KK06

KK07

KK08

KK09

KK10

 

 

 

C

 

S

 

Cl

 

P

 

Fe

 

 

Ti

 

Zn

 

Cr

 

Al.

 

Mn

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Fig. 6.1. Combination of pollutants in the test samples of the Kandalakshes plaster

Microscopic studies have shown some variation in plaster samples. They were found in the paint (creams in samples 02 and 09, red in samples 04 and 07, fig. 6.6), sand grains (samples 03, 05), plants (sample 08), solids (samples 01, 02, 04, 08–10) and metallic dust (samples 01, 02, 04, 05, 08, 10) including 06-rust sample.

129

Microelectrode studies using EDS enabled the determination of the carbon compounds in samples 04 and 10 and sulfur (samples 05–10, figs. 6.8, tabs 6.1–6.10), chlorine (samples 01 and 07) of phosphorus (samples 02–05 and 08, 09). In addition, metals such as iron (all samples), titanium (samples 04.05 and 07.08), zinc (samples 05 and 07), chromium (samples 05 and 06).

The analyzes carried out by ICP-OAS revealed the following content of selected metals: in the case of zinc the highest amounts of this element were found in samples 09 and 02 where they reached 700ppm (Gorki and Piervomajska ul). The zinc values in the other samples are quite varied, in samples 08 and 04 (Pionierskaya ul and 50 years Oktiabria) exceed 200ppm, for samples 03 and 06 exceed 100ppm (Ul Piervomajskaya, Aeronavtov), for samples 05.07 and 10 under 100 Ppm and lowest value of 83ppm for sample 01 (Danilova ul). For manganese, the highest values were found for sample 04 (50 Liet Oktiabria Street), up to 500ppm; in other samples the value of this metal was 300ppm and the lowest value of 66ppm was found in sample 03 (piervomajskaya street, opposite the Hotel Bielomorie). The iron content of the two samples exceeded 10,000 ppm (01 from Danilova St. and 09 from ul. Gorki) in the remaining samples remained at different levels. Sample 04 (Piervomayskaya Str) at 9tys ppm, sample 02 at 7,000ppm, samples 05–08 (Aeronavtov, Pionierskaya) at 6tys ppm, and samples 03 and 10 (puteyskaya ul) at 2tys ppm. For copper the maximum content of this element was found in sample 01 (ul danilova) at 66 ppm; in the other samples it was half as low and the lowest content of 8 ppm was found in sample 03 (Piervomajskaya St, opposite the Hotel Bielomorie). In the case of arsenic this content is not large. Maximum for tests 07 (7.69 ppm), 10 and 05 at 6 ppm (ul Aeronavtov, Puteyskaya and Danilova), while in the remaining trials it was maintained at 4ppm, the lowest values for sample 03 (0.86ppm) from the hotel area Belomorye. The amount of lead also shows some variation in the samples tested. Most of this metal was found for Sample 07 (ul Aeronavtov) 435ppm and Sample 02 (Piervomayskaya Str) 176ppm in other samples was 43ppm (sample 04), 10–12ppm (samples 01, 03, 05, 06) and marginal values for samples 08–10. For nickel content, the highest values were found for sample 1 (Danilova ul) – 28ppm and 02, 08, 09 (Pionierskaya ul. Gorky) within 10 ppm for the remaining sample values below 10ppm and for sample 4.47ppm. In the case of chromium only in sample 08 (from Pionierska Street) these values exceeded 100ppm in the remaining samples remaining within the range of 20– 30ppm and the lowest reaching for samples 01 and 06 approaching 10ppm. Titan was the most abundant in sample 01 (Danilova ul) 4867ppm, in other trials this value was determined in the limit of 3tys ppm and in sample 03 the lowest reached 1735ppm. In case of cadmium, the highest was in sample 08 (Pionierskaya ul) of 8.18 ppm, and in sample 02. 6.62 ppm, while for other samples the value was around 5ppm and the lowest was for samples 02 and 10. 2.30 ppm.

130

Соседние файлы в предмете [НЕСОРТИРОВАННОЕ]